| An-Najah University Journal for Research - Natural Sciences (A) ISSN: 1727-2114 | |
| Volume 7 , 1992, Pages: 29-34 | |
| |
Polarographic Study of Some Arylidene-2-Pyridylhydrazones | |
| Ali Z. Abu-Zuhri, Mohammed A. Al-Nuri, Mohammed A. Hannoun, and Jamal S. Shalabi | |
| Present address: Department of Chemistry, Faculty of Science, United Arab Emirates University, Al-Ain, UAE; This work is taken from the M. Sc. Thesis of Jamal S. Shalabi Department of Chemistry, Faculty of Science, An-Najah National University - Nablus. | |
| Received : 00-00-0000 , Accepted : 00-00-0000 | |
| Language: English | |
Abstract | |
The polarographic behaviors of some arylidene-2-pyridyl hydrazones have been studied in aqueous Britton - Robinson buffer solution containing 40% ethanol using DC polarographic technique। In the pH range 1.9 - 6.4 the observed single irreversible 4 - electron reduction wave is attributed to the splitting of the N - N bond and saturation of C = N centre. All compounds studied are polarographically inactive in alkaline medium. The effect of pH on the limiting current and E 112 as well as the reduction mechanism and the effect of substituent's are discussed and compared with similar compounds. The kinetic parameters of the electrode reaction have been calculated. http://www.najah.edu/index.php?page=2149&l=en&extra=%26id%3D505 | |
Thursday, December 3, 2009
Polarographic Study of Some Arylidene-2-Pyridylhydrazones
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